Table 2.  Total number of analyses from quality-assurance samples during water year 1998 with the number greater than two and six standard deviations from the most probable value and results of statistical testing for analytical precision in constituent data for the National Water Quality Laboratory

[>2SD, number of analyses greater than 2 or less than –2 standard deviations from the most probable value; >6SD, number of analyses greater than 6 or less than –6 standard deviations from the most probable value; WWR, whole-water recoverable; TITR, electrometric titration; --, acceptable results; DIS, dissolved; ICP-AES, inductively coupled plasma-atomic emission spectrometry; ICP-MS, inductively coupled plasma-mass spectrometry; DCP-AES, direct current plasma-atomic emission spectrometry; HG-AAS, hydride generation-atomic absorption spectrophotometry; GF-AAS, graphite furnace-atomic absorption spectrophotometry; USEPA, U.S. Environmental Protection Agency; IC, ion chromatography; LL, low level; GRAV, gravimetric; ISE, ion-selective electrode; F-AAS, flame-atomic absorption spectrophotometry; CV-AAS, cold vapor-atomic absorption spectrophotometry; LOP, statistically significant lack of precision; ELEC, electrometric; COL, colorimetric; ASF, micro-Kjeldahl digestion, automated segmented flow, colorimetric]

 

Constituent and

method of analysis

Number of analyses

p-value

Results from 1998

 

Total

>2SD

>6SD

 

INORGANIC CONSTITUENTS

Alkalinity (WWR,TITR)

241

1

0

1.00000

--

Aluminum (DIS, ICP-AES)

31

0

0

0.79609

--

Aluminum (DIS, ICP-MS)

96

0

0

0.99273

--

Aluminum (WWR, DCP-AES)

37

5

1

0.03593

--

Antimony (DIS, HG-AAS)

12

1

0

0.45964

--

Antimony (DIS, ICP-MS)

96

0

0

0.99273

--

Arsenic (DIS, HG-AAS)

72

1

0

0.97511

--

Arsenic (WWR, GF-AAS, USEPA)

8

0

0

0.33658

--

Arsenic (WWR, HG-AAS)

41

0

0

0.87791

--

Barium (DIS, ICP-AES)

97

0

0

0.99309

--

Barium (DIS, ICP-MS)

96

0

0

0.99273

--

Beryllium (DIS, ICP-AES)

73

0

0

0.97635

--

Beryllium (DIS, ICP-MS)

96

0

0

0.99273

--

Boron (DIS, ICP-AES)

161

0

0

0.99974

--

Boron (WWR, DCP-AES)

12

1

0

0.45964

 

Cadmium (DIS, GF-AAS)

48

1

0

0.91474

--

Cadmium (DIS, ICP-AES)

62

2

0

0.82275

--

Cadmium (DIS, ICP-MS)

96

0

0

0.99273

--

Cadmium (WWR, GF-AAS)

73

2

1

0.88549

--

Calcium (DIS, ICP-AES)

241

0

0

1.00000

--

Chloride (DIS, IC)

241

4

0

0.99816

--

Chloride (DIS, IC, LL)

12

1

1

0.45964

--

Chromium (DIS, GF-AAS)

48

1

0

0.91474

--

Chromium (DIS, ICP-AES)

59

0

0

0.95151

--

Chromium (DIS, ICP-MS)

96

0

0

0.99273

--

Chromium (WWR, GF-AAS)

49

0

0

0.91901

--

Cobalt (DIS, GF-AAS)

8

0

0

0.33658

--

Cobalt (DIS, ICP-AES)

29

3

0

0.17512

--

Cobalt (DIS, ICP-MS)

64

0

0

0.96248

--

Cobalt (WWR, GF-AAS)

25

0

0

0.72261

--

Copper (DIS, GF-AAS)

37

0

0

0.85011

--

Copper (DIS, ICP-AES)

49

0

0

0.91901

--

Copper (DIS, ICP-MS)

64

0

0

0.96248

--

Copper (WWR, GF-AAS)

54

2

1

0.75921

--

Dissolved Solids (DIS, GRAV)

239

4

0

0.99801

--

Fluoride (DIS, IC, LL)

13

1

1

0.48666

--

Fluoride (DIS, ISE)

236

3

0

0.99950

--

Iron (DIS, ICP-AES)

191

0

0

0.99994

--

Iron (WWR, F-AAS)

73

3

0

0.71332

--

Lead (DIS, GF-AAS)

48

1

1

0.91474

--

Lead (DIS, ICP-AES)

10

3

0

0.01150

--

Lead (DIS, ICP-MS)

96

0

0

0.99273

--

Lead (WWR, GF-AAS)

73

2

0

0.88549

--

Lithium (DIS, ICP-AES)

97

0

0

0.99309

--

Lithium (WWR, F-AAS)

13

0

0

0.48666

--

Magnesium (DIS, ICP-AES)

241

2

0

0.99994

--

Manganese (DIS, ICP-AES)

191

0

0

0.99994

--

Manganese (DIS, ICP-MS)

96

0

0

0.99273

--

Manganese (WWR, F-AAS)

43

0

0

0.88982

--

Mercury (DIS, CV-AAS)

48

3

0

0.43295

--

Mercury (WWR, CV-AAS)

48

6

3

0.03171

--

Molybdenum (DIS, GF-AAS)

12

0

0

0.45964

--

Molybdenum (DIS, ICP-AES)

16

2

0

0.18924

--

Molybdenum (DIS, ICP-MS)

96

0

0

0.99273

--

Molybdenum (WWR, GF-AAS)

24

1

1

0.70801

--

Nickel (DIS, GF-AAS)

24

1

0

0.70801

--

Nickel (DIS, ICP-AES)

33

1

0

0.81597

--

Nickel (DIS, ICP-MS)

96

0

0

0.99273

--

Nickel (WWR, GF-AAS)

49

2

1

0.71012

--

Potassium (DIS, F-AAS)

241

6

2

0.98243

--

Potassium (DIS, F-AA, LL)

13

0

0

0.48666

--

Selenium (DIS, HG-AAS)

108

2

0

0.97375

--

Selenium (WWR, GF-AAS, USEPA)

8

0

0

0.33658

--

Selenium (WWR, HG-AAS)

41

0

0

0.87791

--

Silica (DIS, COL)

120

4

2

0.85559

--

Silica (DIS, ICP-AES)

240

0

0

1.00000

--

Silver (DIS, GF-AAS)

16

0

0

0.55987

--

Silver (DIS, ICP-AES)

30

2

0

0.44646

--

Silver (DIS, ICP-MS)

64

11

0

0.00031

LOP

Silver (WWR, GF-AAS)

33

4

1

0.08081

--

Sodium (DIS, ICP-AES)

241

0

0

1.00000

--

Specific Conductance (WWR, ELEC, LL)

13

1

0

0.48666

--

Strontium (DIS, ICP-AES)

97

0

0

0.99309

--

Sulfate (DIS, IC)

241

1

0

1.00000

--

Vanadium (DIS, ICP-AES)

52

0

0

0.93056

--

Zinc (DIS, ICP-AES)

53

4

0

0.27287

--

Zinc (DIS, ICP-MS)

96

0

0

0.99273

--

Zinc (WWR, F-AAS)

73

1

0

0.97635

--

 

NUTRIENT CONSTITUENTS

Ammonia as nitrogen (DIS, COL)

333

30

2

0.00153

LOP

Ammonia as nitrogen (DIS, COL, LL)

66

1

1

0.96613

--

Ammonia as nitrogen (DIS, USEPA)

17

1

0

0.58188

--

Ammonia plus organic nitrogen as nitrogen (DIS, ASF)

334

5

1

0.99982

--

Ammonia plus organic nitrogen as nitrogen (DIS, USEPA)

34

0

0

0.82518

--

Ammonia plus organic nitrogen as nitrogen (WWR, ASF)

226

1

0

0.99999

--

Ammonia plus organic nitrogen as nitrogen (WWR, USEPA)

34

1

0

0.82518

--

Nitrate plus nitrite as nitrogen (DIS, COL)

334

21

3

0.16875

--

Nitrate plus nitrite as nitrogen (DIS, COL, LL)

66

2

1

0.84850

--

Orthophosphate as phosphorus (DIS, COL)

332

52

8

0.00000

LOP

Orthophosphate as phosphorus (DIS, COL, LL)

66

3

3

0.64727

--

Phosphorus (DIS, ASF)

334

21

2

0.16875

--

Phosphorus (DIS, COL, LL)

33

4

2

0.08081

--

Phosphorus (DIS, USEPA)

34

1

0

0.82518

--

Phosphorus (WWR, ASF)

226

3

0

0.99923

--

Phosphorus (WWR, COL, LL)

65

5

3

0.22479

--

Phosphorus (WWR, USEPA)

34

0

0

0.82518

--

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