Table 5.Results of statistical testing for analytical precision in constituent data for the Quality of Water Service Unit laboratory

[DIS, dissolved; --, acceptable results; WWR, whole-water recoverable; TITR, electrometric titration; GF-AAS, graphite furnace-atomic absorption spectrophotometry; ICP-AES, inductively coupled plasma-atomic emission spectrometry; IC, ion chromatography; GRAV, gravimetric; ISE, ion-selective electrode; ICP-AES/T, inductively coupled plasma-atomic emission spectrometry, trace; CV-AAS, cold vapor-atomic absorption spectrophotometry; F-AAS, flame-atomic absorption spectrophotometry; LIS, low-ionic strength; LOP, statistically significant lack of precision]

Constituent and method of analysis

p-value

Results from 1997

Constituent and method of analysis

p-value

Results from 1997

NUTRIENT CONSTITUENTS

Ammonia as nitrogen (DIS)

0.85760

--

Orthophosphate as phosphorus (DIS)

0.26416

--

Ammonia plus organic nitrogen as nitrogen (DIS)

0.88982

--

Phosphorus (DIS)

0.02218

--

Ammonia plus organic nitrogen as nitrogen (WWR)

0.98348

--

Phosphorus (WWR)

0.01230

--

Nitrate plus nitrite as nitrogen (DIS)

0.88982

--

     

INORGANIC CONSTITUENTS

Alkalinity (WWR, TITR)

0.79313

--

Magnesium (DIS, ICP-AES)

0.98170

--

Aluminum (DIS, ICP-AES)

0.72261

--

Manganese (DIS, ICP-AES)

0.66504

--

Aluminum (WWR, ICP-AES)

0.70801

--

Manganese (WWR, ICP-AES)

0.82518

--

Arsenic (WWR, GF-AAS)

0.78536

--

Mercury (WWR, CV-AAS)

0.51233

--

Barium (DIS, GF-AAS)

0.36975

--

Nickel (DIS, ICP-AES)

0.73648

--

Barium (DIS, ICP-AES)

0.58188

--

Nickel (WWR, GF-AAS)

0.43120

--

Barium (WWR, ICP-AES)

0.70801

--

Nickel (WWR, ICP-AES)

0.70801

--

Cadmium (WWR, GF-AAS)

0.82518

--

Potassium (DIS, F-AAS)

0.91033

--

Calcium (DIS, ICP-AES)

0.90658

--

Selenium (WWR, GF-AAS)

0.36975

--

Chloride (DIS, IC)

0.93005

--

Silica (DIS, ICP-AES)

0.94895

--

Chromium (DIS, ICP-AES)

0.73648

--

Silver (DIS, GF-AAS, LIS)

0.55987

--

Chromium (WWR, ICP-AES)

0.72261

--

Silver (DIS, ICP-AES)

0.26491

--

Copper (DIS, ICP-AES)

0.73648

--

Silver (WWR, ICP-AES)

0.51233

--

Copper (WWR, GF-AAS)

0.43120

--

Silver (WWR, ICP-AES/T)

0.40126

--

Copper (WWR, ICP-AES)

0.70801

--

Sodium (DIS, F-AAS)

0.36110

--

Dissolved solids (DIS, GRAV)

0.94895

--

Strontium (DIS, ICP-AES)

0.35762

--

Fluoride (DIS, ISE)

0.98722

--

Strontium (DIS, ICP-AES/T)

0.00493

LOP

Iron (DIS, ICP-AES)

0.97096

--

Strontium (WWR, ICP-AES)

0.51233

--

Iron (WWR, ICP-AES)

0.65944

--

Strontium (WWR, ICP-AES/T)

0.40126

--

Iron (WWR, ICP-AES/T)

0.53671

--

Sulfate (DIS, IC)

0.98722

--

Lead (DIS, GF-AAS)

0.72261

--

Zinc (DIS, ICP-AES)

0.73648

--

Lead (WWR, GF-AAS)

0.49635

--

Zinc (WWR, ICP-AES)

0.82518

--

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