Table 3.Total number of analyses from quality-assurance samples during water year 1997 with number greater than two and six standard deviations from the most probable value for the Quality of Water Service Unit laboratory

[>2SD, number of analyses greater than 2 or less than –2 standard deviations from the most probable value; >6SD, number of analyses greater than 6 or less than –6 standard deviations from the most probable value; DIS, dissolved; WWR, whole-water recoverable; TITR, electrometric titration; GF-AAS, graphite furnace-atomic absorption spectrophotometry; ICP-AES, inductively coupled plasma-atomic emission spectrometry; IC, ion chromatography; GRAV, gravimetric; ISE, ion-selective electrode; ICP-AES/T, inductively coupled plasma-atomic emission spectrometry, trace; CV-AAS, cold vapor-atomic absorption spectrophotometry; F-AAS, flame-atomic absorption spectrophotometry; LIS, low-ionic strength]

Constituent and method of analysis

Number of analyses

Constituent and method of analysis

Number of analyses

Total

>2SD

>6SD

Total

>2SD

>6SD

NUTRIENT CONSTITUENTS

Ammonia as nitrogen (DIS)

38

0

0

Orthophosphate as phosphorus (DIS)

20

2

0

Ammonia plus organic nitrogen as nitrogen (DIS)

43

0

0

Phosphorus (DIS)

22

4

0

Ammonia plus organic nitrogen as nitrogen (WWR)

80

1

0

Phosphorus (WWR)

39

6

0

Nitrate plus nitrite as nitrogen (DIS)

43

0

0

       

INORGANIC CONSTITUENTS

Alkalinity (WWR, TITR)

58

2

0

Magnesium (DIS, ICP-AES)

78

1

0

Aluminum (DIS, ICP-AES)

25

0

0

Manganese (DIS, ICP-AES)

45

2

0

Aluminum (WWR, ICP-AES)

24

0

0

Manganese (WWR, ICP-AES)

34

0

0

Arsenic (WWR, GF-AAS)

30

1

0

Mercury (WWR, CV-AAS)

34

2

1

Barium (DIS, GF-AAS)

17

0

0

Nickel (DIS, ICP-AES)

26

0

0

Barium (DIS, ICP-AES)

9

0

0

Nickel (WWR, GF-AAS)

11

0

0

Barium (WWR, ICP-AES)

24

0

0

Nickel (WWR, ICP-AES)

24

0

0

Cadmium (WWR, GF-AAS)

34

0

0

Potassium (DIS, F-AAS)

79

2

0

Calcium (DIS, ICP-AES)

78

2

0

Selenium (WWR, GF-AAS)

9

0

0

Chloride (DIS, IC)

85

2

0

Silica (DIS, ICP-AES)

58

0

0

Chromium (DIS, ICP-AES)

26

0

0

Silver (DIS, GF-AAS, LIS)

16

0

0

Chromium (WWR, ICP-AES)

25

0

0

Silver (DIS, ICP-AES)

6

0

0

Copper (DIS, ICP-AES)

26

0

0

Silver (WWR, ICP-AES)

14

0

0

Copper (WWR, GF-AAS)

11

1

0

Silver (WWR, ICP-AES/T)

10

0

0

Copper (WWR, ICP-AES)

24

0

0

Sodium (DIS, F-AAS)

79

5

0

Dissolved solids (DIS, GRAV)

58

0

0

Strontium (DIS, ICP-AES)

25

2

1

Fluoride (DIS, ISE)

85

0

0

Strontium (DIS, ICP-AES/T)

23

5

0

Iron (DIS, ICP-AES)

69

1

0

Strontium (WWR, ICP-AES)

14

0

0

Iron (WWR, ICP-AES)

21

0

0

Strontium (WWR, ICP-AES/T)

10

0

0

Iron (WWR, ICP-AES/T)

15

0

0

Sulfate (DIS, IC)

85

0

0

Lead (DIS, GF-AAS)

25

0

0

Zinc (DIS, ICP-AES)

26

1

0

Lead (WWR, GF-AAS)

33

2

2

Zinc (WWR, ICP-AES)

34

0

0

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